
TY  - JOUR
A1  - Bowmaker, GA 
A1  - Hannan, SF 
T1  - The vibrational spectra and structure of the 1 : 1 hexamethylenetetraminebromine complex
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1972
VL  - 25
IS  - 6
SP  - 1151
EP  - 1158
KW  - 
UR  - https://doi.org/10.1071/CH9721151 
N2  - The i.r. and Raman spectra of the crystalline 1 : 1 complex of hexamethylenetetramine (hx) with bromine have been obtained, and these suggest that the solid consists entirely of (hx)2Br+ and Br3- ions. A structure similar to that found for other bis(amine)halogen(r) ions is proposed for the previously unreported (hx)2Br+ ion, and a method is given for the preparation of its perchlorate. The i.r. spectrum of this compound, and that of the I : 2 hx-bromine complex, have also been obtained, and these support the proposed ionic structure for the 1 : 1 complex. 
ER  -

