
%0 Journal Article
%A Subramanian, MS 
%A Pai, SA 
%A Manchanda, VK 
%T Complexes of uranyl &#946;-diketonates with sulphoxides
%J Australian Journal of Chemistry
%D 1973/01/01
%V 26
%N 1
%P 85-89
%K 
%R https://doi.org/10.1071/CH9730085
%U https://www.publish.csiro.au/paper/CH9730085 
%X The proton magnetic resonance spectra of the synergistic complexes of uranyl &#946;-diketonates with dihexyl sulphoxide as the neutral donor give a multiplet consisting of eight lines for the terminal methylene group protons adjacent to the sulphur atom of the sulphoxide and a triplet for the &#946;-methylene protons. This conforms to an ABX2 pattern arising as a result of nonequivalence of the two protons of the terminal methylene group as a result of steric hindrance to free rotation about the C-S bond. The presence of such restricted rotation has been adduced as evidence for a direct donor-metal bond. 
