
TY  - JOUR
A1  - Green, RW 
A1  - Bell, B 
T1  - Complex nickel nitrites. I. Complexes of N-substituted Propane-1,3-diamines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 8
SP  - 1663
EP  - 1668
KW  - 
UR  - https://doi.org/10.1071/CH9731663 
N2  - Complex nickel(II) nitrites, NiLn(NO2)2, can be prepared in good yield by the reaction of amines with K4Ni(NO2)6. Bonding of the NO2 group depends on the nature of the amine. Paramagnetic, octahedral complexes of propane-1,3-diamine (pn) and some of its N-alkyl derivatives were: pn, n = 2, dinitro; N-methyl derivative, n = 2, dinitrito; N-ethyl, n = 2, dinitrito; N,N-dimethyl, n = 1, dinitrito with bidentate nitrito groups. Corresponding thiocyanate complexes were all NiL2(NCS)2. Homopiperazine gave diamagnetic, square-planar complexes, NiL22+, for all anions examined. 
ER  -

