
%0 Journal Article
%A Coutts, RSP 
%A Martin, RL 
%A Wailes, PC 
%T The metal-metal interaction in binuclear Bis(cyclopentadienyl)titanium(III) halides
%J Australian Journal of Chemistry
%D 1973/10/01
%V 26
%N 10
%P 2101-2104
%K 
%R https://doi.org/10.1071/CH9732101
%U https://www.publish.csiro.au/paper/CH9732101 
%X Measurements of the temperature dependence (80-380 K) of the magnetic susceptibility of polycrystalline bis(&#951;-cyclopentadienyl)titanium(III) halides [(&#951;-Cp)2- TiX2Ti(&#951;-Cp)2] with X = F, Cl, Br, and I are reported. Characteristic singlet-triplet behaviour is observed with the strength of the Ti-Ti d1-d1 interaction increasing in the sequence F < Cl &#8776; I < Br. The position of I &#8776; Cl is unexpected and structural data will be required to resolve this anomaly. 
