
%0 Journal Article
%A Buckley, PD 
%A Furness, AR 
%A Jolley, KW 
%A Pinder, DN 
%T c. Internal rotation of the nitroso group in p-substituted nitrosoanilines by the density matrix line-shape method
%J Australian Journal of Chemistry
%D 1974/01/01
%V 27
%N 1
%P 21-26
%K 
%R https://doi.org/10.1071/CH9740021C
%U https://www.publish.csiro.au/paper/CH9740021C 
%X Density matrix theory has been applied to study the barrier to internal rotation about the Ar-NO bond in N,N-dimethyl-p-nitrosoaniline and N,N-diethyl-p-nitrosoaniline. Theoretical fits to experimental n.m.r. spectra have been obtained in the range - 30&#176;C to +40&#176;C. Activation parameters have been determined and compared with those obtained by more approximate methods. 
