
%0 Journal Article
%A Lincoln, SF 
%A West, RJ 
%T A nitrogen-14 magnetic resonance study of the exchange of acetonitrile on cobalt(II) complexes
%J Australian Journal of Chemistry
%D 1974/01/01
%V 27
%N 1
%P 97-103
%K 
%R https://doi.org/10.1071/CH9740097
%U https://www.publish.csiro.au/paper/CH9740097 
%X A 14N N.M.R. study of the exchange of acetonitrile on high-spin Co(triol)(MeCN)32+ (kex = (23 ± 2) x 104 s-1 at 298 K; &#916;H? = 40 ± 2 kJ mol-1; &#916;S? = -9.6 ± 6.2 J mol-1 K-1), high-spin Co(trenol)(MeCN)~2+ (kex &#8805; 2-x 106 s-l at 223 K), and low-spin Co(cyclam)(MeCN)n2+ (where it is considered that n = 1 or 2 and kex &#8805; 8 x 106 s-1 at 266 K) is reported, as are the magnetic moments and visible spectra of these complex ions. 
