
TY  - JOUR
A1  - Radom, L 
T1  - <I>Ab initio</I> molecular orbital calculations on acetyl cations. Relative hyperconjugative abilities of C-X bonds
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 2
SP  - 231
EP  - 239
KW  - 
UR  - https://doi.org/10.1071/CH9740231 
N2  - Ab initio molecular orbital calculations have been carried out for the substituted acetyl cations RCO+ (R = CH3, CH3CH2, (CH3)2CH, (CH3)3C) and XCH2CO+ (X = CH3CH2, CH2=CH,CH=C, C=N, OH, F). The stabilities of the ions RCO+ are found to follow the normal inductive order of the substituents R. The calculations suggest that C-C hyper-conjugation is more effective than C-H hyper-conjugation. 
ER  -

