
TY  - JOUR
A1  - Fergusson, JE 
A1  - Heveldt, PF 
T1  - The influence of &#960;-bonding and steric factors on helahalogeno-metallates
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 3
SP  - 661
EP  - 663
KW  - 
UR  - https://doi.org/10.1071/CH9740661 
N2  - A comparison of the asymmetric stretching frequency v3 and unit cell length a0 for a series of hexahalogeno-metallates A2MX6 [A = K+, Rb+, Cs+ and NH4+, M = Ru, Os, Sn and Te and X = Cl,Br] has been made. Trends observed for the tellurium and tin compounds may be related to stericfactors whereas possible M &#8594; X d&#960;-p&#960; bonding may explain the opposite trend found for ruthenium and osmium compounds. 
ER  -

