
%0 Journal Article
%A Natarajan, GS 
%A Venkatachalam, KA 
%T Correlations of thermodynamic data with structural parameters for cation olefin complexation
%J Australian Journal of Chemistry
%D 1974/06/01
%V 27
%N 6
%P 1209-1213
%K 
%R https://doi.org/10.1071/CH9741209
%U https://www.publish.csiro.au/paper/CH9741209 
%X Thermodynamic data for formation of complexes of silver and cuprous ion with a series of liquid monoolefins are discussed from the angle of the influence of structural parameters of the olefins on the data. This influence may often be masked when comparing log K values owing to marked changes in &#916;Sº values. Opposing trends in thermodynamic data for desolvation may explain contradictions observed in the literature with increasing alkyl substitution. 
