
TY  - JOUR
A1  - Natarajan, GS 
A1  - Venkatachalam, KA 
T1  - Correlations of thermodynamic data with structural parameters for cation olefin complexation
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 6
SP  - 1209
EP  - 1213
KW  - 
UR  - https://doi.org/10.1071/CH9741209 
N2  - Thermodynamic data for formation of complexes of silver and cuprous ion with a series of liquid monoolefins are discussed from the angle of the influence of structural parameters of the olefins on the data. This influence may often be masked when comparing log K values owing to marked changes in &#916;Sº values. Opposing trends in thermodynamic data for desolvation may explain contradictions observed in the literature with increasing alkyl substitution. 
ER  -

