
TY  - JOUR
A1  - Lamberton, JA 
A1  - Nelson, ER 
A1  - Triffett, ACK 
T1  - The reaction of formaldehyde arylhydrazones with acetic anhydride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 7
SP  - 1521
EP  - 1529
KW  - 
UR  - https://doi.org/10.1071/CH9741521 
N2  - Formaldehyde 2,4-dinitrophenylhydrazone does not react with acetic anhydride, whereas formaldehyde 4-nitrophenylhydrazone affords a complex mixture of products from which formaldehyde N,-acetyl-4-nitrophenylhydrazone, N&#946;-acetyl-4-nitrophenylhydrazine, N&#945;,N&#946;-diacetyl-4-nitrophenylhydrazine and 1,4-di(4'-nitrophenyl)-2,5-endo-methanohexahydro-s-tetrazine have been isolated.Formaldehyde phenylhydrazone reacts with acetic anhydride under mild conditions to give N&#945;,N&#946; diacetylphenylhydrazine,1,4-diphenylhexahydro-2,5-endo-methano-s-tetrazine, 2,5-diacetyl-1,4-diphenylhexahydro-s-tetrazine and two other products C17H20N4O2 and C32H36N8O2 which areconsidered to be (7) and (15) respectively. 
ER  -

