
%0 Journal Article
%A Diggle, JW 
%A Parker, AJ 
%T Liquid junction potentials in electrochemical cells involving a dissimilar solvent junction
%J Australian Journal of Chemistry
%D 1974/08/01
%V 27
%N 8
%P 1617-1621
%K 
%R https://doi.org/10.1071/CH9741617
%U https://www.publish.csiro.au/paper/CH9741617 
%X The liquid junction potential at a number of dissimilar solvent junctions has been determined within the framework of the tetraphenylarsonium tetraphenylborate extrathermodynamic assumption. The junctions investigated were H2O/solvent S, MeCN/solvent S and propylene carbonate (pcar)/solvent S. The liquid junction potentials obtained have primarily been related to solvent-solvent interactions at the junction, being, for water, lowest for an alcohol /H2O junction (10 mV) and the greatest for a dipolar aprotic/H20 junction (100-200 mV). 
