
TY  - JOUR
A1  - Diggle, JW 
A1  - Parker, AJ 
T1  - Liquid junction potentials in electrochemical cells involving a dissimilar solvent junction
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 8
SP  - 1617
EP  - 1621
KW  - 
UR  - https://doi.org/10.1071/CH9741617 
N2  - The liquid junction potential at a number of dissimilar solvent junctions has been determined within the framework of the tetraphenylarsonium tetraphenylborate extrathermodynamic assumption. The junctions investigated were H2O/solvent S, MeCN/solvent S and propylene carbonate (pcar)/solvent S. The liquid junction potentials obtained have primarily been related to solvent-solvent interactions at the junction, being, for water, lowest for an alcohol /H2O junction (10 mV) and the greatest for a dipolar aprotic/H20 junction (100-200 mV). 
ER  -

