
TY  - JOUR
A1  - Bowie, JH 
A1  - Williams, BD 
T1  - Electron impact studies. LXXXVIII. formation of an adduct between the trifluoroacetate anion and perfluoroacetic anhydride by ion cyclotron resonance
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 9
SP  - 1923
EP  - 1927
KW  - 
UR  - https://doi.org/10.1071/CH9741923 
N2  - The gas phase reaction between the trifluoroacetate anion and perfluoroacetic anhydride produces a 1 : 1 adduct. The decompositions of this adduct suggest a tetrahedral species rather than a loose association complex. If this is so, this constitutes the first direct observation of the formation of a tetrahedral intermediate produced by anionic displacement at a carbonyl centre. 
ER  -

