
%0 Journal Article
%A Das, M 
%A Livingstone, SE 
%T Thio derivatives of &#946;-diketones and their metal chelates. XVI. Nickel(II), palladium(II), platinum(II), zinc(II) and cobalt(III) chelates of some new fluorinated Monothio-&#946;-diketones
%J Australian Journal of Chemistry
%D 1974/10/01
%V 27
%N 10
%P 2109-2113
%K 
%R https://doi.org/10.1071/CH9742109
%U https://www.publish.csiro.au/paper/CH9742109 
%X The new fluorinated &#946;-diketones RCOCH2COCF3 (R = p-ClC6H4, m-ClC6H4, m-BrC6H4, m-MeC6H4 and m,p-C1,C6H3) have been prepared. The monothio-&#946;-diketones RC(SH)=CHCOCF3 derived from these &#946;-diketones were also prepared. Complexes of these monothio-&#946;-diketones and of p-FC6H4C(SH)=CHCOCF3 with nickel(11), palladium(11), platinum(11), zinc(11) and coba1t(111) have been prepared and characterized. All the complexes are stable and display sharp melting points. 
