
TY  - JOUR
A1  - Das, M 
A1  - Livingstone, SE 
T1  - Thio derivatives of &#946;-diketones and their metal chelates. XVI. Nickel(II), palladium(II), platinum(II), zinc(II) and cobalt(III) chelates of some new fluorinated Monothio-&#946;-diketones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 10
SP  - 2109
EP  - 2113
KW  - 
UR  - https://doi.org/10.1071/CH9742109 
N2  - The new fluorinated &#946;-diketones RCOCH2COCF3 (R = p-ClC6H4, m-ClC6H4, m-BrC6H4, m-MeC6H4 and m,p-C1,C6H3) have been prepared. The monothio-&#946;-diketones RC(SH)=CHCOCF3 derived from these &#946;-diketones were also prepared. Complexes of these monothio-&#946;-diketones and of p-FC6H4C(SH)=CHCOCF3 with nickel(11), palladium(11), platinum(11), zinc(11) and coba1t(111) have been prepared and characterized. All the complexes are stable and display sharp melting points. 
ER  -

