
TY  - JOUR
A1  - Grant, MW 
A1  - Magee, RJ 
T1  - The reaction between cobalt(II) ions and Pyridine-2-carbaldehyde oxime in aqueous solution
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1974
VL  - 27
IS  - 11
SP  - 2475
EP  - 2482
KW  - 
UR  - https://doi.org/10.1071/CH9742475 
N2  - Pyridine-2-carbaldehyde oxime reacts with cobaltous ion in aqueous solution according to the equation :                        Co2+ + 3LH+1/2O2 &#8594; CoL3 + 2H+ + 1/2H2O2  In the absence of oxygen the ligand can function as oxidant. The rate of formation of the cobalt(III)product appears to involve the rate- determining dimerization of the deprotonated cobalt(II) complex, CoL+. Oxygen has no effect on the rate of reaction. 
ER  -

