
%0 Journal Article
%A Chivers, GE 
%A Cremlyn, RJ 
%A Guy, R 
%A Honeyman, R 
%A Reynolds, P 
%T Some reactions of Quinoline-8- and Ureidobenzene-sulphonyl chlorides
%J Australian Journal of Chemistry
%D 1975/02/01
%V 28
%N 2
%P 413-419
%K 
%R https://doi.org/10.1071/CH9750413
%U https://www.publish.csiro.au/paper/CH9750413 
%X Quinoline-8-sulphonyl chloride (1) with hydrazine, phenylhydrazine and sodium azide gave the corresponding hydrazide (3); phenylhydrazide (4); and azide (12). The hydrazide (3) undergoes facile hydrolysis, in contrast to the rather inert sulphonyl azide (12).     Chlorosulphonation of m- and p-chlorophenylureas was unsuccessful. However, the N,N-di-methylurea (18) reacted with chlorosulphonic acid to give p-(N,N-dimethy1ureido)benzenesulphonyl chloride (19), which has been converted into the hydrazide (21) and the azide (20). Both 3- methyl-4-ureidobenzenesulphonyl azide (25) and the azide (20) failed to add to norbornene, although they did react with triphenylphosphine. 
