
%0 Journal Article
%A Lo, STD 
%A Watts, DW 
%T Chromium(III) complexes in dipolar aprotic solvents. VII. Competitive anation studies with [Cr(Me<sub>2</sub>SO)<sub>6</sub>]<sup>3+</sup> in dimethyl sulphoxide
%J Australian Journal of Chemistry
%D 1975/03/01
%V 28
%N 3
%P 501-504
%K 
%R https://doi.org/10.1071/CH9750501
%U https://www.publish.csiro.au/paper/CH9750501 
%X P.The competitive anation reactions: [Cr(Me2SO)6]3+ + X- + Cl-   [CrCl(Me2SO)5]2+ + Me2SO CrX(Me2SO)5]2+ + Me2SO [CrX(Me2S0)5]2*+ Me2S0 where X- is N3- or SCN- have been studied in Me2SO at one temperature as a function of the concentrations of X- and Cl-. The results are compatible with a dissociative interchange reaction of ion aggregates, and require that ion triplets as well as ion pairs contribute to product formation. The results are consistent with our previous results on the anation of Cr(Me2SO)63+ separately by SCN-, N3- and Cl-. 
