
TY  - JOUR
A1  - Lo, STD 
A1  - Watts, DW 
T1  - Chromium(III) complexes in dipolar aprotic solvents. VII. Competitive anation studies with [Cr(Me<sub>2</sub>SO)<sub>6</sub>]<sup>3+</sup> in dimethyl sulphoxide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 3
SP  - 501
EP  - 504
KW  - 
UR  - https://doi.org/10.1071/CH9750501 
N2  - P.The competitive anation reactions: [Cr(Me2SO)6]3+ + X- + Cl-   [CrCl(Me2SO)5]2+ + Me2SO CrX(Me2SO)5]2+ + Me2SO [CrX(Me2S0)5]2*+ Me2S0 where X- is N3- or SCN- have been studied in Me2SO at one temperature as a function of the concentrations of X- and Cl-. The results are compatible with a dissociative interchange reaction of ion aggregates, and require that ion triplets as well as ion pairs contribute to product formation. The results are consistent with our previous results on the anation of Cr(Me2SO)63+ separately by SCN-, N3- and Cl-. 
ER  -

