
TY  - JOUR
A1  - Khoo, KH 
A1  - Chan, C 
T1  - The standard potential of the silver-silver bromide electrode and ion solvation in t-butyl alcohol + water mixtures at 298.15 K
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 4
SP  - 721
EP  - 728
KW  - 
UR  - https://doi.org/10.1071/CH9750721 
N2  - E.m.f. measurements of the cell                          Pt|H2|HBr(m), ButOH(X), water|AgBr|Ag  have been made at 298.15 K for solvent compositions X = 10, 20, 30, 40, 50 and 70% (w/w) of t-butyl alcohol. These have been used to evaluate the standard potential of the silver-silver bromide electrode and the free energy of transfer, &#916;G°t, of the acid from water to the respective solvent media. These &#916;G°t values, along with those for hydrochloric acid, are briefly discussed in relation to ion solvation.     Mean ionic activity coefficients of hydrobromic acid in the various solvents have also been calculated. 
ER  -

