
%0 Journal Article
%A Ham, NS 
%A Hall, JR 
%A Swile, GA 
%T N.M.R. studies of ligand exchange on acetylacetonatotrimethylplatinum(IV)
%J Australian Journal of Chemistry
%D 1975/04/01
%V 28
%N 4
%P 759-761
%K 
%R https://doi.org/10.1071/CH9750759
%U https://www.publish.csiro.au/paper/CH9750759 
%X A quantitative analysis of the variable-temperature 1H N.M.R. spectra of acetylacetonatotrimethyl-platinum(IV) has been made. In CDCl3 solution the exchange of acetylacetonate ligands is a first-order reaction and proceeds predominantly by dissociation of the dimer into two separated five-coordinate activated complexes. The activation energy is 61.5 ± 0.8 kJ mol-1. 
