
TY  - JOUR
A1  - Ham, NS 
A1  - Hall, JR 
A1  - Swile, GA 
T1  - N.M.R. studies of ligand exchange on acetylacetonatotrimethylplatinum(IV)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 4
SP  - 759
EP  - 761
KW  - 
UR  - https://doi.org/10.1071/CH9750759 
N2  - A quantitative analysis of the variable-temperature 1H N.M.R. spectra of acetylacetonatotrimethyl-platinum(IV) has been made. In CDCl3 solution the exchange of acetylacetonate ligands is a first-order reaction and proceeds predominantly by dissociation of the dimer into two separated five-coordinate activated complexes. The activation energy is 61.5 ± 0.8 kJ mol-1. 
ER  -

