
%0 Journal Article
%A Mahadevappa, DS 
%A Naidu, HMK 
%T Kinetics of oxidation of allyl alcohol by chloramine-T in hydrochloric acid medium: effect of high acid concentrations
%J Australian Journal of Chemistry
%D 1975/04/01
%V 28
%N 4
%P 899-901
%K 
%R https://doi.org/10.1071/CH9750899
%U https://www.publish.csiro.au/paper/CH9750899 
%X The kinetics of oxidation of allyl alcohol by chloramine-T in presence of hydrochloric acid(0.15-0.29M) has been studied. At 0°C the rate is first order with respect to chloramine-T, second order in [H+] and independent of the alcohol concentration. The energy of activation and entropy of activation of the reaction have been found to be 55.6 kJ mol  -1 and -153 J K-1 respectively. A mechanism is proposed. 
