
TY  - JOUR
A1  - Mahadevappa, DS 
A1  - Naidu, HMK 
T1  - Kinetics of oxidation of allyl alcohol by chloramine-T in hydrochloric acid medium: effect of high acid concentrations
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 4
SP  - 899
EP  - 901
KW  - 
UR  - https://doi.org/10.1071/CH9750899 
N2  - The kinetics of oxidation of allyl alcohol by chloramine-T in presence of hydrochloric acid(0.15-0.29M) has been studied. At 0°C the rate is first order with respect to chloramine-T, second order in [H+] and independent of the alcohol concentration. The energy of activation and entropy of activation of the reaction have been found to be 55.6 kJ mol  -1 and -153 J K-1 respectively. A mechanism is proposed. 
ER  -

