
TY  - JOUR
A1  - Hoskins, BF 
A1  - Murphy, CN 
T1  - The stuctural nature of a Bender's salt: an X-ray study of potassium O-methyl monothiocarbonate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 6
SP  - 1195
EP  - 1199
KW  - 
UR  - https://doi.org/10.1071/CH9751195 
N2  - The structure of the Bender's salt, potassium O-methyl monothiocarbonate (C2H3O2S-K+), has been determined by single crystal X- ray diffraction methods. The crystals are monoclinic of space group P21/c with a 6.7295(5), b 6.9438(5), c 11.1520(10) &#506;, &#946; 110.93(2)° and Z 4. The structure was solved using a direct phasing programme in conjunction with the Patterson synthesis and refined by a full-matrix least-squares method to R 0.041 for the 788 independent statistically significant reflections collected by counter methods. The crystals are composed of potassium ions and O-methyl monothiocarbonate anions. Each anion is essentially planar with bond lengths and angles having values very similar to those of related systems. 
ER  -

