
%0 Journal Article
%A Kepert, DL 
%A Trigwell, KR 
%T Eight-coordinate complexes of titanium and niobium tetrachlorides with 1,8- Bisdimethylarsinonaphthalene
%J Australian Journal of Chemistry
%D 1975/06/01
%V 28
%N 6
%P 1245-1248
%K 
%R https://doi.org/10.1071/CH9751245
%U https://www.publish.csiro.au/paper/CH9751245 
%X Titanium and niobium tetrachlorides form the eight-coordinate adducts [TiCl4(naars)2] and[NbCl4(naars)2] with 1,8-bisdimethylarsinonaphthalene. The visible spectrum of the latter compound shows that as a result of the small ?bite? of this bidentate ligand, the order of orbital energies is dxy < dxz, dyz < dx2-y2 < dz2. 
