
%0 Journal Article
%A Bennett, RL 
%A Bruce, MI 
%A Matsuda, I 
%T Cyclometallation reactions. XIV. Some reactions of nitrogen-donor ligands
%J Australian Journal of Chemistry
%D 1975/06/01
%V 28
%N 6
%P 1265-1272
%K 
%R https://doi.org/10.1071/CH9751265
%U https://www.publish.csiro.au/paper/CH9751265 
%X The preparation of ortho-metallated complexes from reactions between MnR(CO)5 (R = Me or CH2Ph) or Li2PdCl4 and the following N-donor ligands is reported: azophenetole [Mn; also Ru, from Ru3(CO)12], Dimethyl Yellow (Pd), 4,4?-azobis(N,N-dimethylaniline) (Mn,Pd), azoxybenzene (Pd), 4,4?-azoxyanisole (Pd), benzylideneazine (Mn), N,N?-dimethylbenzylamine (Mn) and N-benzyl-aniline (Mn). The reactions between MnMe(CO)5 and azoxybenzene and azoxyanisole afford metallated derivatives of the corresponding azo compounds; the former derivative was also obtained from hydrazobenzene and MnMe(CO)5. 
