
TY  - JOUR
A1  - Wilson, JC 
A1  - Bowie, JH 
T1  - Electron impact studies. XCVII. Acetic anhydride[&#945;,&#945;'-D<sub>2</sub>]. Synthesis and negative ion molecule reactions. An ion cyclotron resonance study
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1975
VL  - 28
IS  - 9
SP  - 1993
EP  - 1997
KW  - 
UR  - https://doi.org/10.1071/CH9751993 
N2  - Acetic anhydride[&#945;,&#945;?-D2] has been synthesized in near-quantitative yield by the reaction between acetic acid[&#945;-D] and dicyclohexylcarbodiimide. The gas-phase reaction between the acetate anion and acetic anhydride[&#945;,&#945;-D2] yields a 1 : 1 adduct which decomposes by loss of CH2CO and CHDCO so that kH/kD is 1.2 when the ion- transit time is 10-3-10-4 s, and 2.0 at 10-1-10-2 s. 
ER  -

