
TY  - JOUR
A1  - Hoskins, BF 
A1  - Martin, RL 
A1  - Rohde, NM 
T1  - Mossbauer spectrum, molecular and crystal structure of tin(II) diethyldithiocarbamate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 1
SP  - 213
EP  - 217
KW  - 
UR  - https://doi.org/10.1071/CH9760213 
N2  - The syntheses and Mossbauer spectra of four sulphur-chelated compounds of tin(11) are reported. A single-crystal X-ray structure determination of Sn(dedtc)2 has established that the molecule possesses a strongly distorted trigonal bipyramidal configuration with a sterically active lone pair of electrons occupying an equatorial coordination position. While the Mossbauer quadrupole splitting for tin(11) compounds, in general, is consistent with a sterically active pair of electrons, its magnitude appears to be more sensitive to the nature of the ligand rather than the tin stereochemistry. 
ER  -

