
%0 Journal Article
%A Broomhead, JA 
%A Budge, JR 
%A Grumley, WD 
%A Norman, TR 
%A Sterns, M 
%T The synthesis and characterization of azido and cyanato dithiocarbamato nitrosyl complexes of molybdenum : Reduction of coordinated azide in Azidobis(N,N-diethyldithiocarbamato)(dimethyl sulphoxide)nitrosylmolybdenum
%J Australian Journal of Chemistry
%D 1976/02/01
%V 29
%N 2
%P 275-282
%K 
%R https://doi.org/10.1071/CH9760275
%U https://www.publish.csiro.au/paper/CH9760275 
%X The new complexes [MoL(S2CNR2)2(Me2SO)NO] (R = Et, L = NCO- or N3-; R = Me, L = NCO-) and (R'4N) [MO(NCO)2(S2CNR2)2NO] (R = R' = Et; R = Me, R' = Me or Et) have been isolated following the reactions of cis MO(S2CNR~)2(NO)2] with sodium azide and potassium cyanate. Use of 15N-labelled azide has confirmed that molybdenum bonded to a single nitrogen atom must be involved in the reduction of this ligand to ammonia and dinitrogen in strong acid. 
