
%0 Journal Article
%A Edwards, JD 
%T Chromium(II) reduction of the &#956;-Amido-di-&#956;-hydroxo-bis[triamminecobalt(III)] complex in aqueous perchlorate solution
%J Australian Journal of Chemistry
%D 1976/04/01
%V 29
%N 4
%P 915-919
%K 
%R https://doi.org/10.1071/CH9760915
%U https://www.publish.csiro.au/paper/CH9760915 
%X The kinetics of the reduction of [(NH3)3Co,&#956;(NH2,0H,0H),Co(NH3)3]3+ by chromium(11) ion in aqueous perchlorate solution is reported. The results are interpreted in terms of a rapid pre-equilibrium involving hydrogen-ion catalysed hydroxo bridge cleavage, followed by rate determining inner-sphere reduction. A deprotonated aqua ligand is the bridge for electron transfer. 
