
%0 Journal Article
%A Kee, T 
%A Powell, HKJ 
%T Oxygenation of a cobalt(II)-dioxime complex
%J Australian Journal of Chemistry
%D 1976/04/01
%V 29
%N 4
%P 921-923
%K 
%R https://doi.org/10.1071/CH9760921
%U https://www.publish.csiro.au/paper/CH9760921 
%X The ligand 4,4,9,9-tetramethyl-5,8-diazadodecane-2,dione dioxime (LH2) forms cobalt(11) complexes [Co(LH)(H2O)2]+ and [Co(LH)(H2O)OH]; the stabilities of these complexes have been determined in aqueous solution at 25ºC (I = 0.10 M NaCl). The hydroxo complex [Co(LH)(H2O)-OH] reacts with dioxygen to give the non-labile oxygen adduct [(H0)(HL)CoO2Co(LH) (OH)] in aqueous solution: this reaction has been followed by polarographic oxygen sensor. 
