
TY  - JOUR
A1  - Kee, T 
A1  - Powell, HKJ 
T1  - Oxygenation of a cobalt(II)-dioxime complex
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 4
SP  - 921
EP  - 923
KW  - 
UR  - https://doi.org/10.1071/CH9760921 
N2  - The ligand 4,4,9,9-tetramethyl-5,8-diazadodecane-2,dione dioxime (LH2) forms cobalt(11) complexes [Co(LH)(H2O)2]+ and [Co(LH)(H2O)OH]; the stabilities of these complexes have been determined in aqueous solution at 25ºC (I = 0.10 M NaCl). The hydroxo complex [Co(LH)(H2O)-OH] reacts with dioxygen to give the non-labile oxygen adduct [(H0)(HL)CoO2Co(LH) (OH)] in aqueous solution: this reaction has been followed by polarographic oxygen sensor. 
ER  -

