
%0 Journal Article
%A Baker, JR 
%A Lawlor, JM 
%T The mechanism of reaction of phosphoramidate monoanions with nucleophiles
%J Australian Journal of Chemistry
%D 1976/05/01
%V 29
%N 5
%P 949-956
%K 
%R https://doi.org/10.1071/CH9760949
%U https://www.publish.csiro.au/paper/CH9760949 
%X The kinetics of reaction of the N-(4-chlorophenyl)phosphoramidate monoanion in hydroxylamine buffer require an intermediate common to hydrolysis and hydroxylaminolysis. The intermediate is possibly an induced-dipole pair analogous to the ion pairs suggested for substitution at saturated carbon. The same type of intermediate may be a feature of the reactions of all phosphoramidate monoanions and of phosphate monoester monoanions and dianions. 
