
TY  - JOUR
A1  - Baker, JR 
A1  - Lawlor, JM 
T1  - The mechanism of reaction of phosphoramidate monoanions with nucleophiles
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 5
SP  - 949
EP  - 956
KW  - 
UR  - https://doi.org/10.1071/CH9760949 
N2  - The kinetics of reaction of the N-(4-chlorophenyl)phosphoramidate monoanion in hydroxylamine buffer require an intermediate common to hydrolysis and hydroxylaminolysis. The intermediate is possibly an induced-dipole pair analogous to the ion pairs suggested for substitution at saturated carbon. The same type of intermediate may be a feature of the reactions of all phosphoramidate monoanions and of phosphate monoester monoanions and dianions. 
ER  -

