
TY  - JOUR
A1  - Beckwith, ALJ 
A1  - Hawthorne, DG 
A1  - Solomon, DH 
T1  - Cyclopolymerization. XII. Electron spin resonance studies of the free radical reactions of &#946;-substituted diallylamines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 5
SP  - 995
EP  - 1003
KW  - 
UR  - https://doi.org/10.1071/CH9760995 
N2  - E.s.r. spectra, and the effects of different &#946;-substituents on the structures and relative proportions of isomeric pyrrolidin-3-ylmethyl and piperidin-3-yl radicals formed during cyclization of N,N-diallylmethylamines, are described. The hypothetical intermediate 4-azahept-6-en-2-yl radicals undergo preferential cyclization to pyrrolidin-3-ylmethyl radicals, but the sensitivity of this process to steric and conjugative effects is shown by the tendency of intermediate radicals derived from suitable substituted diallylamines to undergo alternative cyclization to piperidin-3-yl radicals. 
ER  -

