
TY  - JOUR
A1  - Angyal, SJ 
A1  - Bethell, GS 
A1  - Cowley, DE 
A1  - Pickles, VA 
T1  - Equilibria between pyranoses and furanoses. IV. 1-Deoxyhexuloses and 3-hexuloses
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 6
SP  - 1239
EP  - 1247
KW  - 
UR  - https://doi.org/10.1071/CH9761239 
N2  - The equilibrium compositions of 1-deoxy-D-fructose, 1-deoxy-L-sorbose, 1-deoxy-L-psicose, D-threopentulose, D-arabino- and L-xylo-3-hexulose and coriose in aqueous solution have been determined by 13C N.M.R. spectroscopy. In all but the last case, considerable amounts of the acyclic keto form are present at equilibrium. The hydrated keto form was not detected; a model compound, l-deoxy- 3,4,5,6-tetra-O-methyl-D-fructose, was found not to be hydrated in aqueous solution. 
ER  -

