
TY  - JOUR
A1  - Lamberton, JA 
A1  - Nelson, ER 
T1  - The reaction of formaldehyde with mixtures of arylhydrazines and amines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 8
SP  - 1853
EP  - 1857
KW  - 
UR  - https://doi.org/10.1071/CH9761853 
N2  - Phenylhydrazine, aniline and formaldehyde react under appropriate conditions to give a high yield of phenyl(phenylazoethyl)amine (1). Under analogous conditions N-methyl-N-phenylhydrazine, N-methylaniline and formaldehyde give 2-(N-methy1anilino)acetaldehyde methylphenylhydrazone (2). With morpholine and phenylhydrazine formaldehyde gives a product C24H34N6O2 considered from spectroscopic evidence to be 2,5-di(morpholinomethyl)-1,4-diphenylhexahydro-s-tetrazine (4) derived from an N-Mannich reaction between morpholine and 1,4-diphenylhexahydro-s-tetrazine.A change in the relative proportions of phenylhydrazine, aniline and formaldehyde results in the formation of a further compound C44H46N10 considered from spectroscopic data to be 2,5-di[Nphenyl-N-(phenylazoethyl)aminomethyl]-l,4-diphenylhexahyo-s-tetrazine (7) derived from an N-Mannich reaction between phenyl(phenylazoethyl)amine (1) and 1,4-diphenylhexahydro-stetrazine. 
ER  -

