
TY  - JOUR
A1  - Mitra, S 
A1  - Raston, CL 
A1  - White, AH 
T1  - Crystal structure of Tris(N,N-dibutyldithiocarbamato)iron(III) benzene solvate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1976
VL  - 29
IS  - 9
SP  - 1899
EP  - 1904
KW  - 
UR  - https://doi.org/10.1071/CH9761899 
N2  - The crystal structure of the title compound, [Fe(CS2NBu2)3],C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 'observed' reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction. 
ER  -

