
%0 Journal Article
%A Dilli, S 
%A Patsalides, E 
%T Volatility studies of metal chelates. II. Gas chromatographic properties of vanadium &#946;-diketonates
%J Australian Journal of Chemistry
%D 1976/11/01
%V 29
%N 11
%P 2381-2388
%K 
%R https://doi.org/10.1071/CH9762381
%U https://www.publish.csiro.au/paper/CH9762381 
%X The gas chromatographic elution behaviour is reported for a total of 16 vanadium(111) and oxovanadium(1V) fluorinated &#946;-diketonates on a column consisting of a lightly loaded, non-polar stationary phase and diatomite support. The superiority of the vanadium(111) chelates is shown to include electron-capture detection. Detection limits of 14 chelates are given for the flame ionization detector. Separation of the two oxidation states of a metal by gas-liquid chromatography is demonstrated for the first time. 
