
TY  - JOUR
A1  - Paul, RC 
A1  - Sharma, R 
A1  - Puri, T 
A1  - Kapoor, R 
T1  - Formic acid solvent system. II. Conductance and solvation studies of 1 : 1 electrolytes in formic acid
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 3
SP  - 535
EP  - 541
KW  - 
UR  - https://doi.org/10.1071/CH9770535 
N2  - Conductances of some 1 : 1 electrolytes have been measured in the concentration range (5-100) x 10-3 mol l-1 in anhydrous formic acid at 25°. The conductance data have been analysed by Fuoss-Shedlovsky equations. Transference numbers of sodium and potassium formates have been measured in this solvent at 25° by a modified Hittorf's method in the concentration range (3-80) x mol l-1. Ionic mobilities, effective ionic radii and solvation numbers of various ions in solution have been calculated. Solvation of cations decreases with the increase in the crystal radii of the ions. 
ER  -

