
TY  - JOUR
A1  - Hewitt, DG 
A1  - Newland, GL 
T1  - Organophosphorus compounds. P-Arylated perhydro-1,2-azaphosphorines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 3
SP  - 579
EP  - 587
KW  - 
UR  - https://doi.org/10.1071/CH9770579 
N2  - Treatment of ethyl 4-bromobutylphosphonochloridate with phenylmagnesium bromide, followed by acid-catalysed hydrolysis of the product, gave 4- bromobutyl(phenyl)phosphinic acid. This was converted into the corresponding phosphinamide by treatment with thionyl chloride and then with aqueous ammonia. Cyclodehydrobromination with sodium hydride in warm xylene then gave a good yield of 2-phenylperhydro-1,2- azaphosphorine 2-oxide. Some other routes to this compound were investigated. 
ER  -

