
%0 Journal Article
%A Hall, SR 
%A Raston, CL 
%A White, AH 
%T Crystal structure of Hydroxyimino(N,N'-dimethyl)malonamide
%J Australian Journal of Chemistry
%D 1977/09/01
%V 30
%N 9
%P 1929-1936
%K 
%R https://doi.org/10.1071/CH9771929
%U https://www.publish.csiro.au/paper/CH9771929 
%X The crystal structure of the title compound, namely hydroxyimino(N,N?- dimethyl)malonamide (MeNHCOC(=NOH)CONHMe), has been determined by single-crystal X-ray diffraction with diffractometer data at 295 K. The structure was solved by direct methods and refined by least squares to a residual of 0.055 for 1477 observed reflections.     Crystal data: monoclinic, P21/n, a 15.508(3), b 10.544(2), c 9.377(1) &#506;, &#946; 103.15(2)°, Z 8.     The two crystallographically independent molecules exhibit little conjugation throughout the C-C-C skeleton (<C-C> 1.50 &#506;), the molecule being non-planar. <C=O> is 1.234, <N-CH3> 1.443, <OC-N> 1.323, <C-NO> 1.278 and (N-O) 1.375 &#506;. The geometry is compared with those observed for several related derivatives. 
