
TY  - JOUR
A1  - Blunt, JW 
A1  - Boyd, GS 
A1  - Hartshorn, MP 
A1  - Munro, MHG 
A1  - Pannell, LK 
T1  - The acid-catalysed dehydration of 13&#945;-Substituted-13&#946;-methylpodocarpan-8&#946;-ols
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 9
SP  - 2015
EP  - 2021
KW  - 
UR  - https://doi.org/10.1071/CH9772015 
N2  - Acid-catalysed dehydration of each of the 8&#946;-hydroxy compounds (1a) and (1b) gives initially the &#916;7 (3), &#916;8(14) (4) and &#916;8 (5) olefins. After extended reaction times the rearranged 8&#945;-&#916;5(16), 8&#945;-&#916;5(10) (14) and 8&#946;- &#916;5(10) (15) olefins are major products; the 8&#946;-&#916;5(10) olefin (15) is the only significant product of long-term acid treatment of the 8&#946;-alcohol (1b) or of the other olefins (3b), (4b), (5b), (14b) and (16b). 
ER  -

