
%0 Journal Article
%A Fenby, DV 
%T Deuterium exchange in water-methanol systems: Calculation of equilibrium constants
%J Australian Journal of Chemistry
%D 1977/11/01
%V 30
%N 11
%P 2371-2375
%K 
%R https://doi.org/10.1071/CH9772371
%U https://www.publish.csiro.au/paper/CH9772371 
%X Equilibrium constants for a number of water-alcohol deuterium exchange reactions in the gas phase are calculated from harmonic frequencies of CH3OH, CH3OD, CD3OH and CD3OD obtained from recent infrared studies. These are combined with vapour-pressure isotope effects to give equilibrium constants for the same reactions in the liquid phase. Calculated equilibrium constants agree well with most published experimental values. 
