
TY  - JOUR
A1  - Fenby, DV 
T1  - Deuterium exchange in water-methanol systems: Calculation of equilibrium constants
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1977
VL  - 30
IS  - 11
SP  - 2371
EP  - 2375
KW  - 
UR  - https://doi.org/10.1071/CH9772371 
N2  - Equilibrium constants for a number of water-alcohol deuterium exchange reactions in the gas phase are calculated from harmonic frequencies of CH3OH, CH3OD, CD3OH and CD3OD obtained from recent infrared studies. These are combined with vapour-pressure isotope effects to give equilibrium constants for the same reactions in the liquid phase. Calculated equilibrium constants agree well with most published experimental values. 
ER  -

