
%0 Journal Article
%A Skelton, BW 
%A White, AH 
%T Crystal structure of Bromo(tetraphenylporphyrin)iron(III)
%J Australian Journal of Chemistry
%D 1977/12/01
%V 30
%N 12
%P 2655-2660
%K 
%R https://doi.org/10.1071/CH9772655
%U https://www.publish.csiro.au/paper/CH9772655 
%X The crystal structure of bromo(tetraphenylporphyrin)iron(III), BrFe{C20N4H8(C6H5)4}, has been determined at 295 K by X-ray diffraction and refined by least squares to a residual of 0.052 (2689 ?observed? reflections). Crystals are monoclinic, P21/c, a 10.191(2), b 16.121(5), c 23.223(4) &#506;, &#946; 115.34(1)°, Z 4. The iron atom lies out of the N4 plane of the porphyrin ligand by 0.49 &#506;, <Fe-N> being 2.069 &#506;; the apex of the five-coordinate square-pyramidal coordination sphere about the iron is occupied by the bromine [Fe-Br 2.348(2) &#506;]. 
