
%0 Journal Article
%A Kucharski, ES 
%A McWhinnie, WR 
%A White, AH 
%T Crystal structure of Bis(tri-2-pyridylamine)iron(II) diperchlorate
%J Australian Journal of Chemistry
%D 1978/01/01
%V 31
%N 1
%P 53-56
%K 
%R https://doi.org/10.1071/CH9780053
%U https://www.publish.csiro.au/paper/CH9780053 
%X The crystal structure of the title compound, [Fe((C5H4N)3N)2] (ClO4)2, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.059 (1995 'observed' reflections). Crystals are monoclinic, P21/a, a 12.815(4), b 17.503(7), c 8.318(3) &#506;, &#946; 121.38(3)&#176;, Z 2. The complex cation lies with the metal atom on a centre of symmetry, the metal being six-coordinate, so that only one of the tridentate ligands is crystallographically independent. The geometry about the metal atom deviates only trivially from octahedral, <N-Fe-N> within the one ligand being 88.1&#176;. <Fe-N> is 1.982 &#506;. 
