
TY  - JOUR
A1  - Kucharski, ES 
A1  - McWhinnie, WR 
A1  - White, AH 
T1  - Crystal structure of Bis(tri-2-pyridylamine)iron(II) diperchlorate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 1
SP  - 53
EP  - 56
KW  - 
UR  - https://doi.org/10.1071/CH9780053 
N2  - The crystal structure of the title compound, [Fe((C5H4N)3N)2] (ClO4)2, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.059 (1995 'observed' reflections). Crystals are monoclinic, P21/a, a 12.815(4), b 17.503(7), c 8.318(3) &#506;, &#946; 121.38(3)&#176;, Z 2. The complex cation lies with the metal atom on a centre of symmetry, the metal being six-coordinate, so that only one of the tridentate ligands is crystallographically independent. The geometry about the metal atom deviates only trivially from octahedral, <N-Fe-N> within the one ligand being 88.1&#176;. <Fe-N> is 1.982 &#506;. 
ER  -

